I've been trying to figure out what some examples of "self-adjoint" functors are, or when this even happens, since I've never seen this before. What I mean is if $F: \mathcal{C} \to \mathcal{C}$ is a functor, then $F$ is self-adjoint if we have the natural bijection
$$
\text{Hom}_{\mathcal{C}}(F(A), B) \cong \text{Hom}_{\mathcal{C}}(A, F(B))
$$
for all objects $A, B \in \mathcal{C}$.
In terms of the unit/counit language, the universal diagrams would be as below.
(Forgive the abuse of $f$ and $g$.) The second half of this question is the following: Is $(-)^{\text{op}}: \textbf{Cat} \to \textbf{Cat}$ an example? I think so. This is because $(\mathcal{A}^{\text{op}})^{\text{op}}= \mathcal{A}$ for any category $\mathcal{A}$. Hence we can take the $\eta_{\mathcal{A}} = \epsilon_{\mathcal{A}} = 1_{\mathcal{A}}$, so the unit and counits are trivial. The unique existence of a functor completing the commutative triangles is just given by $(-)^{\text{op}}$, e.g., if we have a functor $g: \mathcal{A} \to \mathcal{B}^\text{op}$, then take $f = g^{\text{op}}: \mathcal{B} \to \mathcal{A}^{\text{op}}$. The diagram on the above left commutes, and similar reasoning gives us the counit diagram on the right. However, this example seems a bit trivial that happens to work out because $(-)^{\text{op}}$ is a nice functor; hence my question regarding more interesting examples.