No. If you have an n dimensional space, and you have n linearly independent vectors, the it must form a basis for the space.
A set of vectors spanning a space is a basis iff it is the minimum number of vectors needed to span the space.
So if you reduce the number of vectors in your basis, it is no longer a basis for $R^n$ but will instead form a basis for $R^{n-1}$
You can prove this more rigorously by writing any $x \in V$ as the sum of vectors from your linearly independent list and showing that if you remove one vector from the list you can no longer do this, as you cannot write the nth element as some sum of the other elements.