I am assuming that the product measure is the one induced by the product outer measure. (This avoids any issue with ambiguity of definition.)
Any set of the form $B \times A$, with $B$ Borel is measurable ($A$ is arbitrary).
Take the sets $S_n = \{(1,1)\} \cup\left( \cup_{k=0}^{n-1} [\frac{k}{n},\frac{k+1}{n})^2 \right)$. Clearly each $S_n$ is measurable, and hence $D = \cap_{n \ge 0} S_n $ is measurable.
We must have $(m \times \mu) D = \infty$.
To see this, suppose
$D \subset \bigcup_{n \ge 0} B_n \times A_n$, where $B_n$ is Borel, and $A_n$ is arbitrary. Let $D_n = D \cap (B_n \times A_n)$, and let $\pi_x((x,y)) = x$ and similarly $\pi_y((x,y)) = y$. Since $[0,1] \subset \cup_n \pi_x D_n$, we must have $m^* (\pi_x D_{n'} ) >0$ for some $n'$, where $m^*$ is the Lebesgue outer measure (using $m^*$ avoids having to worry about the measurability of $\pi_x D_{n'}$).
Hence $m B_{n'} \ge m^* (\pi_x D_{n'} ) > 0$. In addition, $\pi_x D_{n'}$ must be uncountable (otherwise $m^* (\pi_x D_{n'} ) $ would be zero). Furthermore, $\pi_y D_{n'} = \pi_x D_{n'}$, $\pi_y D_{n'} \subset A_{n'}$, hence $A_{n'}$ is also uncountable. Hence $m(B_{n'}) \mu(A_{n'}) = \infty$, and so $\sum_{n \ge 0} m(B_{n}) \mu(A_{n}) = \infty$ for any cover of $D$ by measurable rectangles. Hence $(m \times \mu) D = (m \times \mu)^* D =\infty$.