Concavity of Sine
For $x,y\in[0,\pi]$,
$$
\begin{align}
\frac{\sin(x)+\sin(y)}2
&=\sin\left(\frac{x+y}2\right)\cos\left(\frac{x-y}2\right)\\[6pt]
&\le\sin\left(\frac{x+y}2\right)\tag1
\end{align}
$$
Since $\sin(x)$ is continuous, $(1)$ shows that $\sin(x)$ is concave on $[0,\pi]$.
The Inequality
Note that for $x=0$ and $x=\frac\pi4$, $\sin(x)=\frac{2\sqrt2x}\pi$. Thus, since $\sin(x)$ is concave on $\left[0,\frac\pi4\right]$, we have
$$
\sin(x)\ge\frac{2\sqrt2x}\pi\tag2
$$
for $x\in\left[0,\frac\pi4\right]$. Thus, for $\frac x2\in\left[0,\frac\pi4\right]$, that is, $x\in\left[0,\frac\pi2\right]$,
$$
\begin{align}
\cos(x)
&=1-2\sin^2\left(\frac x2\right)\tag3\\
&\le1-\frac{4x^2}{\pi^2}\tag4
\end{align}
$$
where step $(4)$ is simply an application of $(2)$. Since $(4)$ is even, it is true for $x\in\left[-\frac\pi2,\frac\pi2\right]$. Therefore, for $\frac\pi2-x\in\left[-\frac\pi2,\frac\pi2\right]$, that is, $x\in[0,\pi]$,
$$
\begin{align}
\sin(x)
&=\cos\left(\frac\pi2-x\right)\tag5\\
&\le1-\frac{4\left(\frac\pi2-x\right)^2}{\pi^2}\tag6\\
&=1-\left(\frac{2x}\pi-1\right)^2\tag7
\end{align}
$$
where $(6)$ is an application of $(4)$.