Background: suppose $F:G\to H$ is a homomorphism of Lie groups. Then, there is an induced homomorphism $F_*:\mathfrak g\to \mathfrak h$ defined by
$Y_h:=(F_*X)_h=d(L_h\circ F_e)X_e \tag1\label{eq:1}$
This definition is the one it makes sense to use because it makes $X$ and $Y\ F$-related.
Now, if $X\in \mathfrak g,$ we have $X_e=\gamma'(0)$ where $\gamma(t)=\exp tX$, which means that
$(F_*X)_e=dF_e(X_e)=dF_e(\gamma'(0))=\frac{dF(\exp tX)}{dt}|_{t=0}\tag{2}\label{eq:2}$
Now, apply \eqref{eq:1} and \eqref{eq:2} to the following data: fix $g\in G$ and set $C_g:G\to G: x\mapsto gxg^{-1}$ and $\text{Ad}:G\to GL(\mathfrak g):g\mapsto (C_g)_*.$ Then, $\text{Ad}_*:\mathfrak g\to \mathfrak gl(\mathfrak g)$ satisfies
$(\text{Ad}_*X)_Y=d(L_Y\circ \text{Ad}_e)X_e \tag{3}\label{eq:3}$
$(\text{Ad}_*X)_e=\frac{d\text{Ad}(\exp tX)}{dt}|_{t=0}\tag{4}\label{eq:4}$
My question is simply this: in the course of his proof, Lee has instead of \eqref{eq:4} the following equation
$\text{Ad}_*X=\frac{d\text{Ad}(\exp tX)}{dt}|_{t=0}\tag{5}\label{eq:5}$
which does not make sense to me. Now, if we take $X$ to be a vector in $T_eG$, then we can find a curve $c$ in $G$ such that $c'(0)=X$ and so we get
$\text{Ad}_*X=\frac{d\text{Ad}(c(t))}{dt}|_{t=0}\tag{6}\label{eq:6}$
and so if we take $c=\gamma$ where $\gamma(t)=\exp tX$, we get \eqref{eq:5}. But then, we are considering $X$ to be a left-invariant vector field again. Is this type of argument legitimate? If so, why? If not, why not?
I believe my confusion is that although the definition of the induced homomorphism $F_*X$ on a Lie algebra is obviously not the same as $(F_*X)_e$ and yet in defining the adjoint representation, Lee uses the former, in which case, I do not see clearly how $(5)$ obtains, whereas in another proof I have seen, one defines $\text{ad}(X) = (d \text{Ad})_e(X)$ (and then proves that $\text{ad}(X)Y=[X,Y]$) and then $(5)$ is just a consequence of the definiton. But of course, $(d \text{Ad})_e(X)\neq \text{Ad}_*X$.