From the continued fraction expansion of $\pi$, we have
$$
\frac{333}{106}\lt\frac{103993}{33102}\lt\pi\lt\frac{355}{113}\;.
$$
There are various ways of proving these inequalities without using decimal approximations:
In the case of $\mathrm e$, the continued fraction expansion is regular and can be systematically derived (see e.g. A Short Proof of the Simple Continued Fraction Expansion of e by Henry Cohn, The American Mathematical Monthly, $113(1)$, $57$–$62$, The Simple Continued Fraction Expansion of e by C. D. Olds, The American Mathematical Monthly, $77(9)$, $968$–$974$, or Continued fraction for e at Topological Musings); it yields
$$
\frac{1264}{465}\lt\mathrm e\lt\frac{1457}{536}\;.
$$
Thus it suffices to show that
$$
\left(\frac{1457}{536}\right)^\frac{355}{113}+\frac1{\frac{333}{106}}\lt\left(\frac{103993}{33102}\right)^\frac{1264}{465} + 1\;,
$$
or
$$
\left(\frac{1457}{536}\right)^\frac{355}{113}\lt\left(\frac{103993}{33102}\right)^\frac{1264}{465} + \frac{227}{333}\;.
$$
Since both sides contain fractional exponents, it’s hard to compare them directly; but we can find a fraction that lies between them and compare them to it separately. Among the suitable fractions, the one with the lowest denominator is $\frac{4767}{206}$. The rational inequalities
$$
\left(\frac{1457}{536}\right)^{355}\lt\left(\frac{4767}{206}\right)^{113}
$$
and
$$
\left(\frac{4767}{206}-\frac{227}{333}\right)^{465}\lt\left(\frac{103993}{33102}\right)^{1264}
$$
are readily checked with integer arithmetic, and thus with
$$
\left(\frac{1457}{536}\right)^\frac{355}{113}\lt\frac{4767}{206}\lt\left(\frac{103993}{33102}\right)^\frac{1264}{465} + \frac{227}{333}
$$
the result follows.