Aspects of probability space and random variable I am trying to make sense of various aspects of a probability space and a random variable and how they relate, and would like some help to tie it all together/ verify my understanding this far:
Consider a probability space $(\Omega, \mathcal{F,P})$, that models a random experiment, for example: flipping a fair coin twice.
A sample space $\Omega$ contains objects (could be "non-mathematical" objects), also referred to as outcomes of the random experiment, for example: $\Omega = \{HH, HT, TH, TT\}$
A sigma algebra $\mathcal{F}$ (of our choice) contains subsets of $\Omega$ called events i.e. subsets of "non-mathematical" objects, for example: $\mathcal{F}=\{\varnothing,\{TT\},\{HT,TH,HH\},\{HH,HT,TH,TT\}\}$, or, another example: $\mathcal{F}=\mathscr{P}(\Omega)$ (i.e. the power set of $\Omega$).
A probability measure $\mathcal{P}$ (of our choice) assigns probabilities to the events i.e. assignes probabilities to the subsets of "non-mathematical" objects in $\mathcal{F}$, 
for example: $\mathcal{P}$ could be defined as: $P(\{\varnothing\})=0$, $P(\{TT\})=0.25$, $P(\{HT,TH,HH\})=0.75$, $P(\{HH,HT,TH,TT\})=1$. 
(In the case of a fair coin).
A random variable $X$ (of our choice) maps some or all of the events in $\mathcal{F}$ to values (in a measurable space $(E,\mathcal{E})$), for example: a random variable $X$ has the following mappings: $\{TT\}$ is mapped to 1, $\{HT,TH,HH\}$ is mapped to 2, $\{HH,HT,TH,TT\}$ is mapped to 3. 
And, the probabilities given to the events in $\mathcal{F}$ by $\mathcal{P}$ are "transfered"/ "pushed forward" to the values of $X$ in $(E, \mathcal{E})$, for example: $P({TT})=0.25 = f(x=1)$, where $f(x)$ is the pmf of $X$.
Clarification 1: Given any combination of mutually exclusive events in $\mathcal{F}$ there should exist an associated probability distribution, which should be the "same" as the probability distribution of a random variable that assigns values to that specific combination of mutually exclusive events, right?
Clarification 2: And as such the probability measure $\mathcal{P}$ in regard to a combination of mutually exclusive events in $\mathcal{F}$ should be the "same" as the pmf/pdf of a random variable that maps those events to values, only the inputs to $\mathcal{P}$ are events instead of values (like with the pmf/pdf). Correct?
 A: You can specify the same event in multiple ways. For example suppose the sample space is the set of outcomes of two flips of a coin: 
$$ \Omega = \{HH, HT, TH, TT\}$$
The sigma-algebra $\mathcal{F}$ is the set of all subsets of $\Omega$. 
Now define a random variable $Y:\Omega\rightarrow\mathbb{R}$ as the number of heads:
$$ Y(HH) = 2 , Y(HT) = 1, Y(TH)=1, Y(TT)=0$$
The following are different ways of specifying the same event: 
$$\{\mbox{there are 2 heads}\} =  \{HH\} = \{\omega \in \Omega : Y(\omega)=2\} = \{Y=2\} $$
All of these are the same event and so of course:
$$P[\mbox{there are 2 heads}]= P[\{HH\}] = P[\{\omega \in \Omega : Y(\omega)=2\}] =  P[Y=2]$$
Because these are all the same event, there is no need to “redefine” or “push-forward” anything.  

If you want to define a function $f:\{0, 1,2\}\rightarrow\mathbb{R}$ by $f(y) = P[Y=y]$, then nobody will stop you.  Since the events $\{Y=0\}$, $\{Y=1\}$, $\{Y=2\}$ partition the sample space (they are disjoint events and their union is the whole sample space), the third axiom of probability ensures 
$$P[Y=0]+P[Y=1]+P[Y=2]=P[\Omega]$$
and we also know $P[\Omega]=1$. 
If you want to write the above equation using your function $f$, then indeed $f(0)+f(1)+f(2)=1$.

If for some reason you want to define a new sample space $\mathcal{Y} = \{0,1,2\}$, sigma algebra $\tilde{\mathcal{F}}$ being the set of all subsets of $\mathcal{Y}$, and probability measure $\tilde{P}[A]$ defined for all $A \subseteq \mathcal{Y}$ by 
$$\tilde{P}[A] = \sum_{y \in A} f(y)$$ 
then nobody will stop you (and you can verify this satisfies the three axioms of probability). 
More generally, if $\mathcal{Z}$ is any finite or countably infinite set and if $g:\mathcal{Z}\rightarrow\mathbb{R}$ is a function that satisfies $g(z)\geq 0$ for all $z \in \mathcal{Z}$ and
$\sum_{z \in \mathcal{Z}}g(z)=1$, then defining the sigma algebra as the set of all subsets of $\mathcal{Z}$ and defining $P:2^{\mathcal{Z}}\rightarrow \mathbb{R}$ by 
$$ P[A] = \sum_{z \in A} g(z) \quad \forall A \subseteq \mathcal{Z}$$
yields a valid probability measure, meaning that all three axioms of probability hold.
