You've got two questions about the absolute Laplace transform, which is defined as
$$\mathcal L_a[f(k)](x)=\int^\infty_{0}f(k)e^{-k|x|}dk$$ for continuous $f(k) \in o(e^{\delta x}), \forall\delta>0$.
Question 1: How to interpret the different behaviour on both sides of the equation under differentiation at $x=0$?
In $\mathbb R$, if there exists a punctured neighbourhood of $x=0$ such that $\mathcal L_a[f](x)$ and $\displaystyle{\sum^\infty_{n=0}a_n x^{2n}}$ coincide , then both expressions have the same behaviour under differentiation at $x=0$, in the sense that
$$\int^\infty_{0}f(k) \left( \frac{\partial}{\partial x} \right)_{\text{left}} e^{-k|x|}dk\bigg\vert_{x\to0^-}
=\int^\infty_{0}f(k) \left( \frac{\partial}{\partial x} \right)_{\text{right}} e^{-k|x|}dk\bigg\vert_{x\to0^+}
=\frac{d}{dx}\sum^\infty_{n=0}a_n x^{2n}\bigg\vert_{x=0}=0
$$
where the subscripts denote the one-sided derivatives.
Sketch of proof:
The third equality is trivial.
To prove the right-sided derivative is zero, we want to switch the order of integral and differentiation. Here we will utilise the 'extended Leibniz integral rule':
For $$\frac{d}{dx}\int^\infty_c f(x,t)dt=\int^\infty_c \frac{\partial}{\partial x} f(x,t)dt\qquad{x\in(a,b)}$$ to be true, the sufficient conditions are
$f(x,t)$ and $\displaystyle{\frac{\partial}{\partial x} f(x,t)}$ are continuous in the region $c\le t<\infty$, $a\le x\le b$.
$\displaystyle{\lim_{N\to\infty}\int^N_c \frac{\partial}{\partial x}f(x,t)dt} $ converges uniformly for $x\in(a,b)$.
$\displaystyle{\lim_{N\to\infty}\int^N_c f(x,t)dt} $ converges for $x\in(a,b)$.
It is straight-forward to prove that the three conditions are satisfied for $0<x<r$ ($r$ is the radius of convergence of the Taylor series). Thus
$$\begin{align}
\int^\infty_{0}f(k) \left( \frac{\partial}{\partial x} \right)_{\text{right}} e^{-k|x|}dk\bigg\vert_{x\to0^+}
&=\left( \frac{d}{dx} \right)_{\text{right}}\int^\infty_{0}f(k)e^{-kx}dk\bigg\vert_{x\to0^+} \\
&=\left( \frac{d}{dx} \right)_{\text{right}}\sum^\infty_{n=0}a_n x^{2n}\bigg\vert_{x\to0^+} \\
&=0
\end{align}
$$
Similarly, the left-sided derivative is also zero.
Note: It is a little bit more complicated to show condition 2 is satisfied.
We aim to prove that for $x>0$, $$\lim_{N\to\infty}\int^N_{0}f(k) \left( \frac{\partial}{\partial x} \right)_{\text{right}} e^{-k|x|}dk=\lim_{N\to \infty}\int^N_{0}-kf(k) e^{-kx}dk\quad\text{converges uniformly.}$$
To this end, we make use of Cauchy criterion:
for sufficiently large $m>n>N$,
$$\begin{align}
\left|\int^m_{n}-kf(k) e^{-kx}dk\right|
&<\int^m_{n}\left|kf(k) e^{-kx}\right|dk \\
&<\int^m_{n}e^{\delta x} e^{-kx}dk \\
&<2\cdot\frac{e^{(\delta-x)n}}{x-\delta} \\
&<2\cdot\frac{e^{(\delta-x)N}}{x-\delta} \\
&<2\cdot\frac{e^{-\Delta N}}{\Delta} \quad \text{for } x>\delta+\Delta, \Delta>0\\
\end{align}
$$
Choosing $N=\frac1{\Delta}\ln\frac 2{\epsilon\Delta}$ would show uniform convergence for $x>\delta+\Delta$, and hence justifying the exchange of differentiation and integral for $x>\delta+\Delta$. By noticing that $\delta,\Delta$ can be chosen to be arbitrarily small, we have shown that condition 2 is satisfied for all $x>0$.
Question 2: Is it possible to differentiate under the integral sign, possibly at the cost of introducing additional terms of distributional nature?
Yes.
Suppose $\mathcal L_a[f](x)$ and $\displaystyle{\sum^\infty_{n=0}a_n x^{2n}}$ coincide in a punctured neighbourhood of $x=0$.
Then, indeed, in the sense of distribution,
$$\int^\infty_0 kf(k)dk=0$$ and thus
$$\frac{d}{dx}\mathcal L_a[f(k)](x)\bigg\vert_{x=0}=-\text{sgn}(x)\int^\infty_0 kf(k)e^{-k|x|}dk\bigg\vert_{x=0}=-\text{sgn}(0)\int^\infty_0 kf(k)dk=0$$
Proof:
It is well-known that $$\int^\infty_0 \delta'(s)e^{-sk}ds=k$$
Therefore,
$$\begin{align}
\int^\infty_0 kf(k)dk
&=\int^\infty_0 \int^\infty_0 \delta'(s)e^{-sk} f(k) \, ds \, dk \\
&=\int^\infty_0 \int^\infty_0 \delta'(s)e^{-sk} f(k) \, dk \, ds \qquad (1)\\
&=\int^\infty_0 \delta'(s)\left(\int^\infty_0 f(k)e^{-sk} dk\right)ds \\
&=\int^\infty_0 \delta'(s)\sum^\infty_{n=0}a_n s^{2n} ds \qquad (2)\\
&=-\int^\infty_0 \delta(s)\left(\sum^\infty_{n=0}a_n s^{2n}\right)' ds \\
&=-\left(\sum^\infty_{n=0}a_n s^{2n}\right)'_{s=0} \\
&=0
\end{align}
$$
$(1)$: Changing order of integrals is justified by Fubini's theorem.
$(2)$: Due to the formula $\displaystyle{\int^\infty_{-\infty}\delta'(x)\varphi(x)dx=-\int^\infty_{-\infty}\delta(x)\varphi'(x)dx}$.