How this equality is verified.
$$\arctan(2\sqrt2)+2\arctan(\sqrt2)=\pi$$
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$$\arctan(2\sqrt2)+2\arctan(\sqrt2)=\pi$$
Using $$\tan(A+B+C)=\dfrac{\tan A+\tan B+\tan C-\tan A\tan B\tan C}{\cdots}$$
$$\tan(\arctan(2\sqrt2)+2\arctan(\sqrt2))=\dfrac{2\sqrt2+\sqrt2+\sqrt2-2\sqrt2(\sqrt2)^2}{\cdots}=0$$
$$\implies\arctan(2\sqrt2)+2\arctan(\sqrt2)$$ must be multiple of $\pi$
Again, as $2\sqrt2,\sqrt2>0$
$$\dfrac\pi2>\arctan(2\sqrt2)>\arctan(\sqrt2)>0$$
$$\implies0<\arctan(2\sqrt2)+2\arctan(\sqrt2)<3\cdot\dfrac\pi2$$
Now what is the multiple of $\pi$ that lies $\in\left(0,3\cdot\dfrac\pi2\right)$
See also: Why does $\tan^{-1}(1)+\tan^{-1}(2)+\tan^{-1}(3)=\pi$?
$$2\arctan\sqrt2=\pi+\arctan\dfrac{2\sqrt2}{1-(\sqrt2)^2}=?$$
Now $\arctan(-x)=-\arctan x$
We can use the sum identity for the tangent function
$$\tan(x\pm y)=\frac{\tan x\pm \tan y}{1\mp \tan x \tan y}$$
to check the given identity by
$$\arctan(2\sqrt2)+2\arctan(\sqrt2)=\pi$$
$$\iff \arctan(2\sqrt2)+\arctan(\sqrt2)=\pi-\arctan(\sqrt2)$$
that is
$$\frac{2\sqrt 2+\sqrt 2}{1-2\sqrt 2 \cdot \sqrt 2}\stackrel{\text{?}}=\frac{0-\sqrt 2}{1+0}$$