Let $X_n$ be a Markov chain on a countable state space $E$. For $x\in E$ let $\tau_x:=\inf\{n\geq 1\vert X_n=x\}$ be the first hitting time.
What can be said about the relation between the transition matrix $p(x,y)$ of the Markov chain and the probability of the first hitting time $\mathbb P(\tau_x =k\vert X_0=y)$?
Is there a general explicit relation or is there a non-trivial class of Markov chains for which the relation can be calculated explicitly?