This is a conjecture emanating from random tests with my set routines written in Forth.
$a>b \;\wedge \pi(a+b)=\pi(a)+\pi(b)\implies b<11$
Furthermore, if $b\in\mathbb N$, then $b\in\{0,1,2,3,4,9,10 \}$
I would like (partly) proofs or counterexamples.
Tested for $b<a<100,000$.
Testing the numbers of hits for the non trivial values of $b$ and for some upper limits:
1 2 3 4 9 10
100 74 48 8 14 2 2
1000 832 332 34 66 4 6
10000 8771 2454 204 406 11 20
100000 90408 19180 1223 2444 37 72
1000000 921502 156992 8168 16334 165 328