Let $K$ be a field, and put $K \text{-vect}$ for the category of $K$-vector spaces. There is an adjunction $[-, K]_{K \text{-vect}} : K \text{-vect}^{op} \leftrightarrow K \text{-vect} : [-, K]_{K \text{-vect}}$ where $[-, K]_{K \text{-vect}}$ sends a vector space $V$ to $[V, K ]_{K \text{-vect}}$, the $K$ vector space of linear maps from $V$ to $K$.
Evidently, the vector space structure on $V^*$ alone is not enough to recover $V$. I wonder, though, about putting a topology on it. For each $a \in V$, there is a map $\hat{a} : V^* \rightarrow K$ sending $\phi$ to $\phi(a)$. Give $V^*$ the weakest topology such that $\hat{a}$ is continuous for each $a \in V$.
Question: form $[V^*, K]_{K \text{-topvect}}$, the vector space of continuous linear maps of topological vector spaces from $V^*$ to $K$. Is this vector space isomorphic to $V$?
If this turns out to be true, then we have a functor $F : K \text{-vect}^{op} \rightarrow K \text{-topvect}$ and a functor $G : K \text{-topvect} \rightarrow K \text{-vect}^{op}$, such that $G \circ F \cong 1_{K \text{-vect}^{op}}$