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In the definition of localization of a ring $R$ where $S$ the multiplicative subset, we say $(a,s) \sim (b,s') \iff \exists t \in S$ such that $t(s'a-sb)=0$.

Why do we require such a $t\in S$?

What if we just say $(a,s) \sim (b,s') \iff s'a-sb=0$?

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    $\begingroup$ Otherwise there is no reason to believe that this is an equivalence relation, as $S$ could contain zero divisors. Rational numbers don't have this problem, because $\mathbb{Z}$ is an integral domain. $\endgroup$ Commented Aug 14, 2019 at 2:23

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The idea is because $\sim$ might not be an equivalence relation otherwise.

If you have $(a,s)\sim (b,s')$ and $(b,s')\sim (c,t)$ in your proposed definition, then $as'-bs=bt-cs'=0$, why does that imply $at-cs=0$?

In the case of integral domains, where you don't need the extra element of $S$, you can just multiply $as'-bs$ by $t$ and $cs'-bt$ by $s$, add the two expressions to cancel out the $bst$, and then factor out the $s'$ and$\textbf{ use the nonexistence of zero divisors}$ to conclude that $at-cs=0$.

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