First suppose $f_1,...,f_n$ is a basis for $V^*$ and $b_1,...,b_n$ is a basis for $V$. Then
the matrix $C$ defined by $[C]_{ij} = f_i(b_i)$ is invertible, and if we let $A=C^{-1}$ then the points $\beta_i = \sum_k [A]_{ik} b_k$ satisfy $f_j ( \beta_i) = \delta_{ij}$.
That is, $f_k$ is the dual basis for $\beta_k$.
Suppose $f_k$ span $V^*$, and $x \in V$. Without loss of generality we can assume
that $f_k$ is a basis for $V^*$. Write $x=\sum_k \alpha_k \beta_k$. Since $\alpha_k = f_k(x)$, we see that if $f_k(x) = 0$ for all $k$ then $x=0$. Hence $\cap_k \ker f_k = \{0\}$.
Now suppose the $f_k$ do not span $V^*$. Without loss of generality we can assume that the $f_k$ are linearly independent. Add functionals $g_j$
such that $f_k,g_j$ form a basis. Construct the basis $\beta_k$ of $V$ as above.
Suppose $g_j(\beta_j) = 1$, then we have $f_k(\beta_j) = 0$ for all $k$ and so
$\beta_j \in \cap_k \ker f_k$.