iid: Independent and Identical Distribution.
If you roll two identical dice, you don't get two identical number($2X$) every time.
$2X$ is not the same as $X+Y$(Sum of two dice). Not even in distribution.
$2X$ will be either 2,4,6,8,10,12, and the probabilities are all the same $\frac{1}{6}$.
However, $X+Y$ will be one of 2,3,4,5,6,7,8,9,10,11,12 and the probabilities are all different.
Pr($X+Y=12$) = $\frac{1}{36}$ but Pr($X+Y=6$) = $\frac{5}{36}$
Indeed this example is famous as an example of the central limit theorem.
Therefore, Var($2X$) $\ne$ Var($X+Y$) is what it is supposed to be.
In fact, Let Var($X$) = $\sigma^2$, then Var($2X$) = 4$\sigma^2$, and Var($X+Y$) = 2$\sigma^2$.
Since we don't distinguish these two dice (identical), ${E}(X|X+Y) ={E}(Y|X+Y) $