I guess you're having a problem with notation. Here is what you could do to try to get the hang of things:
$A$ is the power set of $\left\{1,2,3,4\right\}$; That is $A$ is the set of all subsets of $\left\{1,2,3,4\right\}$. You can write all of these explcitly if you want (there are 16 of them:
$$A=\Big\{\normalsize\varnothing,\ \left\{1\right\},\ \left\{2\right\},\left\{3\right\},\left\{4\right\},\left\{1,2\right\},\ldots,\left\{1,4\right\},\left\{2,3\right\},\ldots\left\{1,2,3,4\right\}\Big\}.$$
This is not necessary but you should definitely do it it you're not comfortable with the description "$A=\mathcal{P}(\left\{1,2,3,4\right\})$.
Now look at your function $f(X)=\left\{1,2,3,4\right\}-X$. In words, $f(X)$ is the complement of $X$, where $X$ is a subset of $\left\{1,2,3,4\right\}$. Again, if you're having difficulties, try to calculate a few random values. For example, let's take a random element $X$ of $A$, say $X=\left\{1,3,4\right\}$. Then
$$f(X)=\left\{1,2,3,4\right\}-\left\{1,3,4\right\}=\left\{2\right\}$$
Cool, so $\left\{2\right\}$ is in the image of $f$. In symbols, I will denote the image of $f$ by $Im(f)$, so
$$Im(f)=\left\{\{2\},\ldots\right\}$$
You can then keep computing $f(X)$ for all 12 possibilities of $X$; here are a few other random values:
$$f(\left\{2\right\})=\left\{1,3,4\right\},\quad f(\left\{1,3\right\})=\left\{2,4\right\},\quad f(\left\{2,4\right\})=\left\{1,3\right\}...$$
so
$$Im(f)=\left\{\{2\},\{1,3,4\},\{1,3\},\{2,4\},\ldots\right\}$$
This should give you the whole of $Im(f)$. It is not too much work because $A$ is small. But if $A$ were a little larger things would get exponentially more time-consuming. (For example, if $A$ were $\left\{1,2,3,4,5,6\right\}$ there would be 64 computations to make!)
So you might have noticed something I did above: $f(\{1,3,4\})=\{2\}$, while $f(\{2\})=\{1,3,4\}$, that is, $f$ is just permuting $\{1,3,4\}$ and its image, $\{2\}$, and similarly $f$ is just permuting $\{1,3\}$ and its image $\{2,4\}$. So you may ask yourself if $f$ is always just permuting $X$ and $f(X)$., that is, if $X=f(f(X))$. To do this, compute
$$f(f(X))=\{1,2,3,4\}-f(X)=\{1,2,3,4\}-(\{1,2,3,4\}-X)),$$
and verify that the right-hand side is equal to $X$ (it is "the complement of the complement").
So after you verify that $X=f(f(X))$ for all $X$, you can conclude that every $X\in A$ is the image of some $Y\in A$; namely $Y=f(X)$. Therefore $A\subseteq Im(f)$, whereas $Im(f)$ is a subset of the codomain $A$ of $f$, i.e.., $Im(f)\subseteq A$. By definition of equality of sets (or ZFC, or an axiom of Naïve Set Theory if you will), $Im(f)\subseteq A$ and $A\subseteq Im(f)$ means precisely that $Im(f)=A$.
The latter determination of $Im(f)$ was formal, without any "computations", and in fact works if we replace $A$ by any set, as large as it is.