As already said, for a rigorous calculation of $a$, you will need some numerical method.
However, we can have quite good approximation since
$$F(a) = \int_{-\infty}^a \frac{1}{\sqrt{2\pi}} \, \exp\left(-\dfrac{x^2}{2} \right) dx=\frac{1}{2} \left(1+\text{erf}\left(\frac{a}{\sqrt{2}}\right)\right)$$
Rewrite is as
$$(2F(a)-1)^2=\left(\text{erf}\left(\frac{a}{\sqrt{2}}\right)\right)^2$$ and have a look here where you will see good approximations
$$\left(\text{erf}\left(x)\right)\right)^2=1-e^{-k x^2}$$ where $k=\frac{\pi^2} 8$ or, (supposed to be slightly better) $k=(1+\pi )^{2/3} \log ^2(2)$. This gives as an approximation
$$a=\sqrt{-\frac{2 \log [4 (1-F(a)) F(a)]}{k} }$$ Appplied to $F(a)=0.95$, the first $k$ would give $$a=\frac{4 \sqrt{\log \left(\frac{100}{19}\right)}}{\pi } \approx 1.64082$$ and the second
$$a=\frac{\sqrt{2 \log \left(\frac{100}{19}\right)}}{\sqrt[3]{1+\pi } \log (2)} \approx 1.63726$$ while the "exact" solution would be $1.64485$
A bit more complex (but this is just a quadratic equation in $x^2$) would use
$$\mathrm{erf}\!\left(x\right)^2\approx1-\exp\Big(-\frac 4 {\pi}\,\frac{1+\alpha x^2}{1+\beta x^2}\,x^2 \Big)$$ where $$\alpha=\frac{10-\pi ^2}{5 (\pi -3) \pi }\qquad \text{and} \qquad \beta=\frac{120-60 \pi +7 \pi ^2}{15 (\pi -3) \pi }$$
Applied to the worked example, this last formula would give $a=1.64528$.
Edit
After comments, the last equation was used for the range $0.90 \leq F(a) \leq 0.99$. The table below gives the results.
$$\left(
\begin{array}{ccc}
F(a) & \text{approximation} & \text{exact} \\
0.90 & 1.28164 & 1.28155\\
0.91 & 1.34087 & 1.34076\\
0.92 & 1.40523 & 1.40507\\
0.93 & 1.47600 & 1.47579\\
0.94 & 1.55507 & 1.55477\\
0.95 & 1.64528 & 1.64485\\
0.96 & 1.75133 & 1.75069\\
0.97 & 1.88180 & 1.88079\\
0.98 & 2.05548 & 2.05375\\
0.99 & 2.32999 & 2.32635
\end{array}
\right)$$