Including rotational motion into a reaction-diffusion model

The reference below describes a system of hypothetical sub-particle units or etherons, diffusing from a region of high to low concentration using Fick’s law of diffusion. How would one introduce rotation or convection into this system?

Reference starts here (1):

2.7 Diffusive Behavior

Besides reactively transforming from one type into another, etherons also move in space. Like molecules in a gas or liquid, etherons exist in a state of random motion continually colliding with one another. Due to their “Brownian motion,” they have a tendency to diffuse from regions of high to low concentration. Just as with molecules, at a given point in space the direction and rate of diffusion of etherons of a given type depends on the direction and steepness of the slope in the prevailing concentration of those etherons. The steeper the concentration gradient, the more rapidly etherons will diffuse down the gradient. This is an example of the Second Law of Thermodynamics at work in nature. Etheron diffusion behavior may be mathematically represented as follows. Let the vector $$\boldsymbol{\nabla} C_i (r)$$ represent the gradient of the concentration $$C_i$$ of specie i at a given point in space, that is, the change in its concentration as a function of distance r. The rate of flow of etherons through a unit of surface area disposed perpendicular to this concentration gradient is denoted as the diffusive flux vector, $$\boldsymbol{\Phi}_i (r)$$. Adopting Fick’s law for molecular diffusion, we postulate that the magnitude of $$\boldsymbol{\Phi}_i (r)$$ varies in direct proportion to the concentration gradient as:

$$\boldsymbol{\Phi}_i (r) = -D_i \boldsymbol{\nabla} C_i (r)$$

where $$D_i$$ is a constant of proportionality called the diffusion coefficient. To calculate the etheron flux in a relative frame of reference in which the ether has a net velocity, $$\boldsymbol{v}$$, the convective flux vector, $$\boldsymbol{v} C_i (r)$$, must also be taken into account, giving a total flux of:

$$\boldsymbol{J}_i (r) = -D_i \boldsymbol{\nabla} C_i (r) + \boldsymbol{v} C_i (r)$$

Depending on the direction of $$C_i$$ relative to $$\boldsymbol{v}$$, these two effects could be either complementary or competitive.

Definitions

Hypothetical sub-particles are quantified by concentration $$C_i(r)$$ and have units $$mol \ m^{-3}$$. There are only 3 sub-particle types i (etherons): $$X(r)$$, $$Y(r)$$ concentrations (components of electrical field - also accounting for magnetic component) and $$G(r)$$ concentrations (gravitational field).

$$\boldsymbol{J}_i (r)$$ is the total diffusive flux vector, of which the dimension is amount of etherons of type i per unit area per unit time, so it is expressed in such units as $$mol \ m^{-2} s^{-1}$$.

$$\boldsymbol{\Phi}_i (r)$$ is the diffusive flux vector, of which the dimension is amount of etherons of type i per unit area per unit time, so it is expressed in such units as $$mol \ m^{-2} s^{-1}$$. $$\boldsymbol{\Phi}_i (r)$$ measures the amount of etherons that will flow through a unit area during a unit time interval.

$$D_i$$ is the diffusion coefficient or diffusivity for etheron type i. Its dimension is area per unit time, so typical units for expressing it would be $$m^2 s^{-1}$$.

$$C_i(r)$$ (for ideal mixtures) is the concentration of etheron type i, of which the dimension is amount of etherons per unit volume. It might be expressed in units of $$mol \ m^{-3}$$.

$$r$$ is position, the dimension of which is length. It might thus be expressed in the unit $$m$$.

$$S_i (r)$$ is the net diffusive flux, of which the dimension is amount of etherons of type i per unit volume per unit time, so it is expressed in such units as $$mol \ m^{-3} s^{-1}$$.

2.8 Etheron Conservation

Earlier (Section 2.1), we noted that etherons are conserved. That is, any change in the number of type-i etherons must be accounted for either by the import or export of type-i etherons from that volume or by the birth or death of type-i etherons through reactive transformation. To mathematically represent this accounting process we must first define a scalar quantity called the net diffusive flux $$S_i$$ which represents the rate at which type-i etherons flow into or out of a given incremental volume through the surface bounding that volume. This rate is expressed as the divergence of the etheron flux vector, $$\boldsymbol{\Phi}_i$$ :

$$S_i = \boldsymbol{\nabla} \boldsymbol{\Phi}_i (r) = -D_i \boldsymbol{\nabla}^2 C_i (r)$$

For a relative reference frame, the above relation should be expanded to include the divergence of the convective flux:

$$S_i = -D_i \boldsymbol{\nabla}^2 C_i (r) + \boldsymbol{v} \cdot \boldsymbol{\nabla} C_i (r)$$

However, for many of the situations we will be considering, we may assume $$\boldsymbol{v} = 0$$ and neglect this second term. The etheron conservation requirement may now be mathematically expressed as:

$$\frac{\partial C_i}{\partial t} = R_i (C_1, C_2, C_3,..., C_n) - S_i(C_i)$$

where $$\partial C_i / \partial t$$ is the net rate of change in the concentration of type-i etherons within a given incremental volume $$dV$$ in the absolute rest frame and within a given increment of absolute time $$dt$$. $$R_i$$ is the net rate of generation of type-i etherons due to etheron reactions taking place within $$dV$$, and $$S_i$$ is the net diffusive flux of type-i etherons flowing out of $$dV$$ (or into $$dV$$) during time $$dt$$.

1. LaViolette, P. A. (2012). Subquantum Kinetics - A Systems Approach to Physics and Cosmology. Starlane Publications, Niskayuna, New York.

If the rotational rate of a fluid particle is,

$$\boldsymbol{\omega} = \frac{1}{2} \boldsymbol{\nabla} \times \boldsymbol{v}_\omega$$

The velocity component $$\boldsymbol{v}_\omega$$ of the angular velocity $$\boldsymbol{\omega}$$ can be added to the total diffusive flux vector $$\boldsymbol{J}_i(r)$$, to account for the rotational motion:

$$\begin{equation} \therefore \boldsymbol{J}_i (r) = -D_i \boldsymbol{\nabla} C_i (r) + \boldsymbol{v}_\omega C_i (r) \end{equation}$$

where $$-D_i \boldsymbol{\nabla} C_i (r)$$ accounts for the translational velocity of the fluid, having dimensions of $$m^{-2}s^{-1}$$

The net diffusive flux ($$mol \ m^{-3} s^{-1}$$) will then be:

$$\begin{equation} S_i = -D_i \boldsymbol{\nabla}^2 C_i (r) + \boldsymbol{v}_\omega \cdot \boldsymbol{\nabla} C_i (r) \end{equation}$$