Start with a Markov matrix $\mathbf{M}$, whose elements are all between $0 \le \mathbf{M}_{ij} \le 1$ and each row sums to one. There is a natural connection with this matrix and the rate matrix $\mathbf{W}$ in the Master Equation
$$ \mathbf{M} = \exp( t \mathbf{W} ) $$
Here, given $\mathbf{W}$, the calculation of $\mathbf{M}$ is unambiguous with $t$ since the matrix exponential is unique and converges by the Taylor expansion. What about the other direction?
$$ t \mathbf{W} = \log( \mathbf{M} ) $$
Do the properties of the Markov matrix guarantee this is unique and that the alternating sum in the log
Taylor series converge?
Please provide a reference where this is discussed if possible!
Motivation (by request)
I've been studying the dynamics assoicated with an Ising model type system under single spin-flip Glauber dynamics. Glauber dynamics gives essentially the $\mathbf{W}$ matrix. If one were to observe the system over a finite time, an approximation to $\mathbf{M}$ could be made. I was interested in when it was permissible to convert between the two. In the reference provided by one of the answers the question boils down to:
In probabilistic terms a Markov matrix A is embeddable if it is obtained by taking a snapshot at a particular time of an autonomous finite state Markov process that develops continuously in time. On the other hand a Markov matrix might not be embeddable if it describes the annual changes in a population that has a strongly seasonal breeding pattern; in such cases one might construct a more elaborate model that incorporates the seasonal variations. Embeddability may also fail because the matrix entries are not accurate; in such cases a regularization technique might yield a very similar Markov matrix that is embeddable;