A geometric series is a sires of the form:
$$\sum_{n = 0}^{\infty} ar^n$$
And the only time such a series converges is when $|r|<1$. In that case, what it converges to can be found using the following formula:
$$
\sum_{n = 0}^{\infty} ar^n=\frac{a}{1-r}
$$
To convert the given series into a geometric one (or ones), just start by shifting the index $n$ down by $1$ to make it begin at $0$:
$$
\sum_{n = 1}^{\infty} \frac{6 - 2^{2n - 1}}{3^n}=
\sum_{n = 0}^{\infty} \frac{6 - 2^{2(n+1) - 1}}{3^n}=
\sum_{n = 0}^{\infty} \frac{6 - 2^{2n+1}}{3^n}=\\
\sum_{n = 0}^{\infty} \left(\frac{6}{3^n}-\frac{2\cdot2^{2n}}{3^n}\right)=
6\sum_{n = 0}^{\infty} \left(\frac{1}{3}\right)^n-2\sum_{n = 0}^{\infty}\left(\frac{4}{3}\right)^n
$$
The first of the two geometric series converges because $|1/3|<1$. The second geometric series diverges because $|4/3|$ is not less then $1$. If one series in a sum diverges, the whole thing diverges.