Let $(x_n)$ be any sequence of positive terms with $\sum x_n$ convergent. Define sequence of positive terms $(a_n)$ as follows:
$$
a_n=\begin{cases}
\frac1{k^2}&\text{if $n=k(k+1)/2$ for some integer $k$} \\
x_n&\text{otherwise}
\end{cases}
$$
So the first few terms of $(a_n)$ are:
$$
\textstyle \frac11,\ x_2,\ \frac14,\ x_4,\ x_5,\ \frac19,\ x_7,\ x_8,\ x_9, \ \frac1{16},\ x_{11},\ x_{12},\ \ldots\tag1
$$
It is clear that $\sum a_n$ converges, since $\sum a_n$ is at most $\sum x_n + \sum_k\frac1{k^2}$.
Now consider any decomposition of the form $a_n=b_n-c_n$ with $(b_n)$ positive and decreasing, and $(c_n)$ positive. We show that $\sum b_n$ cannot converge.
By construction, $b_n> a_n$ for every $n$. In particular, checking the triangular subscripts $n:=k(k+1)/2$, we see $b_1>\frac11$, $b_3>\frac14$, $b_6>\frac19$, $b_{10}>\frac1{16}$. By assumption, $(b_n)$ is decreasing, so the sequence $(b_n)$ must be at least as big (pointwise) as the sequence
$$
\textstyle
\frac11,\ \frac14,\ \frac14,\ \frac19,\ \frac19,\ \frac19,\ \frac1{16},\ \frac1{16},\frac1{16},\ \frac1{16},\ \frac1{25},\ \ldots\tag2
$$
But the sum of the terms (2) is the harmonic series. Therefore $\sum b_n$ diverges.