The standard model of Peano's arithmetic, $\mathbb{N}$, has the useful property that the order $\leq$ is a well-order. However, being a well-order cannot be expressed in the language of first-order Peano arithmetic, because it concerns subsets of numbers, or predicates on numbers, and the first-order logic cannot quantify on those.
In a non-standard Peano model, is the order $\leq$ a well-order ? It seems impossible, because if it was a well-order we could take the smallest non-standard number, and then ask about its predecessor.
But if a non-standard model is not well-ordered, how can we interpret Peano's induction axiom scheme ? It would prove formulas by induction, even though there are infinite descending sequences of non-standard numbers, so nowhere to intuitively initialize the induction.