There are many answers to show examples that a sigma algebra is not necessarily a topology. In answer, it is shown that on every uncountable set there is a $\sigma$-algebra that isn't a topology. In detail:
Let $S$ be any uncountable set, and let $\mathcal{A}$ be the collection of all subsets of $S$ which are either countable or have countable complement.
This collection is evidently closed under complementation. If I have a countable union of elements of $\mathcal{A}$, all of which are countable, then the union is countable. Otherwise, at least one element is cocountable, hence so is the union. A similar argument works for intersections. So $\mathcal{A}$ is a $\sigma$-algebra.
I want to confirm that the basic reason behind this answer. I thought it is because:
$\sigma$-algebra is closed under finite and infinite countable unions; while a topology is closed under finite, infinite countable unions, and infinite uncountable unions. And it is the need of infinite uncountable unions makes some topologies that are not $\sigma$-algebras. Am I right?
Also, I want to confirm when we say "topologies are also closed under arbitrary unions", the arbitrary here means all possible unions: finite unions, infinite countable unions and infinite uncountable unions.