Could it be to help the blind. I know it's not a uk coin, but the 50p and 20p are septagons to aid the blind. The old 10p was a similar size to the 50p; and the of 5p was a similar size to the 20p, so they made them a different shape. Also the 2p was a similar size to the 10p as well, so the 10p have grooves around the edge and the 2p is smooth. Same for the 1p (smooth)and it's similar size to the 5p (groved).
To summarize two groups of coin are a similar size:
1p (smooth edges), 5p (grooved edges), 20p (septagon shape).
And the same for 2p, 10p and 50p, respectively.
The designs were to aid the blind who could feel the coin to know what is was as the sizes were too similar to distinguish.
math-history
is meant for the history of math concepts, not their applications. $\endgroup$