Here's where I encountered this word:
The raw material needed for the manufacture of medicine has to be at least $97\%$ pure. A buyer analyzes the nullhypothesis, that the proportion is $\mu_0=97\%$, with the alternative hypothesis that the proportion is higher than $97\%$. He decides to buy the raw material if the nulhypothesis gets rejected with $\alpha = 0.05$. So if the calculated critical value is equal to $t_{\alpha} = 98 \%$, he'll only buy if he finds a proportion of $98\%$ or higher with his analysis. The risk that he buys a raw material with a proportion of $97\%$ (nullhypothesis is true) is $100 \times \alpha = 5 \%$
I don't really understand what is meant by 'critical value'