Let me have another go at answering the question...
If the formalism is natural deduction, there appears to be no place for the material conditional. The following rule is not a given rule of minimal logic in natural deduction:
$$
\frac{\neg{(P\land\neg Q)}}{P\to Q}
$$
For example, there is no place for the material conditional here:
https://www.cs.cornell.edu/courses/cs3110/2013sp/lectures/lec15-logic-contd/lec15.html
Whilst it might not seem like such a bad idea to define $P\to Q$ as a shorthand for $\neg{(P\land\neg Q)}$ in such systems, this appears never to be done.
On the other hand, away from natural deduction, we should consider $\to$ as a primitive that cannot be defined in terms of other connectives. For example, one form of the principle of explosion is implemented thus...
$$
\neg P\to(P\to Q)
$$
...here:
https://en.wikipedia.org/wiki/Minimal_logic
Compare this with the same in natural deductive form:
$$
\frac{\neg P}{P\Rightarrow Q}
$$
To compare these two directly, however, and therefore to conclude that $\to$ is in some sense the same as both logical consequence and inference, would seem to be wrong.
If we say that the first and last rules given here are in natural deductive style and the second rule is in the Hilbert style (I am not entirely sure that it is but the definition will have to suffice for now), the lesson seems to be that such comparisons between styles can lead to mis-comprehensions. It appears that it is not quite right to believe that it is the same logic underneath, to put it one way.
In Hilbert style logics we have the concept of the material conditional, the single arrow, if that is what we choose to adopt (and many logicians would disagree rightly on this point and insist that it should simply be referred to as implication and is not the same as the material conditional) and it is a primitive of the logic and not defined by any axiom. In natural deduction style logic, on the other hand, we have the primitive notion of inference and, along with that, a definition of logical consequence, the double arrow, that is not a primitive of the logic and that we define with the standard introduction and elimination rules.
So it is not the case that the natural deduction and Hilbert styles are simply two views of the same underlying logic, and it was my mistake to believe that they were.
Much confusion arises because when logicians commonly speak of minimal and intuitionistic logic, they are referring to the Hilbert style, and do not make this clear, even though it is perfectly possible to define variants of minimal and intuitionistic logic in the natural deductive style.
Further confusion arises because it is permissible to define the material conditional in the natural deductive style, but only for classical logic. So, again, it was my mistake to add the introduction and elimination rules for the material conditional to minimal logic given in the natural deductive style. I hadn't pulled the introduction rule out of thin air, my mistake was simply to add it at the minimal level, not the classical one. And at the classical level of course, it is equivalent to logical consequence, the double arrow, anyway, which I why I have omitted it still.
I hope this clarifies.