As we can see that the favourable case are those where sum of pair of two natural numbers is divisible by 4, and such pairs may be listed as below:
\begin{align*} &(0,0), (0,4), (0,8),\\ &(1,3), (1,7),\\ &(2,2), (2,6),\\ &(3,1), (3,5), (3,9)\\ &(4,0), (4,4), (4,8)\\ &(5,3), (5,7)\\ &(6,2), (6,6)\\ &(7,1), (7,5), (7,9),\\ &(8,0), (8,4), (8,8),\\ &(9,3), (9,7). \end{align*} Thus, there are 25 favourable cases where sum of two natural numbers is divisible by 4. Now, for exhaustive cases, we can see that there total 10 natural number viz. 0--9. Therefore, there are 10$\cdot$10=\,100.
Therefore, the probability comes out to be \begin{align*} P=\,\frac{25}{100}=\frac{1}{4}. \end{align*}
Is my approach is correct?