Elements of $\mathbb{R}/2 \mathbb{Z}$ are of the form $x + 2\mathbb{Z}$ for $x \in \mathbb{R}$ and a complete set of representatives is given by choosing $x$ from $[0,2)$, although many other choices are possible.
Elements of $\mathbb{Z}/2 \mathbb{Z}$ are of the form $z + 2\mathbb{Z}$ for $z \in \mathbb{Z}$ and a complete set of representatives is given by choosing $z$ from $\{0,1\}$.
Elements of $G = \frac{\mathbb{R}/2 \mathbb{Z}}{\mathbb{Z}/2 \mathbb{Z}}$ are apparently, then, of the form $x + 2\mathbb{Z} + \mathbb{Z}/2\mathbb{Z}$. We may find all the elements of the equivalence class containing $x$ by \begin{align*}
\bigcup_{z \in \mathbb{Z}/2\mathbb{Z}} & x + 2\mathbb{Z} + z \\
&= \left( x + 2\mathbb{Z} + (0 + 2\mathbb{Z}) \right) \cup \left( x + 2\mathbb{Z} + (1 + 2\mathbb{Z}) \right) \\
&= \left( x + 2\mathbb{Z} \right) \cup \left( x + 1 + 2\mathbb{Z} \right) \\
&= x + (2\mathbb{Z} \cup (1 + 2\mathbb{Z}) ) \\
&= x + \mathbb{Z} \text{.}
\end{align*}
That is, the equivalence classes of the quotient defining $G$ are the same as those in $\mathbb{R}/\mathbb{Z}$ (and addition goes through without complications). So $G \cong \mathbb{R}/\mathbb{Z}$.