For definiteness, let $(S,\mathcal{A})$ be a measure space and $\mathcal{A} \otimes \mathcal{A}$, the corresponding product $\sigma$-algebra on $S \times S$. Recall that if $E \in \mathcal{A} \otimes \mathcal{A}$ and $y \in S$, then the set $E_{y} \subseteq S$ defined by
$$E_{y} = \{x \in S \, \mid \, (x,y) \in E\}$$
satisfies $E_{y} \in \mathcal{A}$. Indeed, if we let $\mathcal{G}$ denote the family
$$\mathcal{G} = \{E \subseteq S \times S \, \mid \, E_{y} \in \mathcal{A}\},$$
then $\mathcal{G}$ is a $\sigma$-algebra on $S \times S$ containing the collection of measurable rectangles $\{A \times B \, \mid \, A,B \in \mathcal{A}\}$. Therefore, $\mathcal{A} \otimes \mathcal{A} \subseteq \mathcal{G}$, proving the claim.
Now if $\Delta \subseteq S \times S$ is the diagonal, then $\Delta_{y} = \{y\}$. Therefore,
$$\forall y \in S \quad \{y\} = \Delta_{y} \in \mathcal{A}.$$