It is well-known that the exponential map associated to any compact connected Lie group is surjective (the proof is a simple application of the Lefschetz fixed point theorem). As it happens, the exponential map associated to $\mathrm{GL}_n(\mathbb{C})$ is also surjective, although $\mathrm{GL}_n(\mathbb{C})$ fails to be compact. The only way I know how to prove this latter claim is by expressing each element of $\mathrm{GL}_n(\mathbb{C})$ in its Jordan canonical form and then showing that any Jordan block is the exponential of some matrix.
My question is this: is there a wider class of Lie groups (more general than just compact and connected, and perhaps including examples like $\mathrm{GL}_n(\mathbb{C})$) for which we can say that the exponential map is surjective?