I suppose the last observation should be 53, not 53!.
Assuming normal data the best estimate of the population mean $\mu$ (not $X$)
is the sample mean $\bar X = 53$, and the best estimate of of the population
SD $\sigma$ is the sample SD $S = 1.4142,$ as you have said.
The answer to the second question depends on the exact interpretation
of "based on these estimates." One way to model the approximate distribution of a predicted seventh observation
is $X_7 \stackrel{aprx}{\sim} \mathsf{Norm}(\bar X, S\sqrt{1 + 1/6}),$ where the second
argument is the population SD. In that case the requested probability is about 0.1. [A similar method is used to predict an additional observation $Y$ after
finding a regression model of $Y$ on $x.$]
Roughly, the rationale for this model of $X_7$ is that one would model
$\bar X \stackrel{aprx}{\sim} \mathsf{Norm}(\bar X, S\sqrt{1/6}),$ but
that the additional observation was not used to find $\bar X$, hence
the estimated SD for $X_7$ is $S\sqrt{1 + 1/6}$.
There are other ways to model an additional observation so you should
verify this method by looking in your text or notes.
Computations in R statistical software follow. If you use standardization
and printed normal tables, you may get a slightly different answer for
the second part.
x = c(51,53,54,55,52,53)
mean(x)
## 53
sd(x)
## 1.414214
1-diff(pnorm(c(50.5,55.5), mean(x), sd(x)*sqrt(1+1/6)))
## 0.1017069
Note: If we ignore the estimates and model the new observation
as $X_7 \sim \mathsf{Norm}(\mu, \sigma)$ (whatever $\mu$ and $\sigma$ may be), then by a simple
combinatorial argument there are 2 chances in 7 that $X_7$ will
be either the minimum or the maximum of the sample of $n+1 = 7$
observations. It does not seem to me that this is the intended approach.