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$\ds{\int_{0}^{1}{1 - x \over 1 + x}\,{2k + 3 + x^{2} \over 1 + x^{2}}
\,{\dd x \over \ln\pars{x}} =
-\ln\pars{2^{k}\pi}:\ {\large ?}.\qquad k \in \mathbb{R}}$.
\begin{align}
&\int_{0}^{1}{1 - x \over 1 + x}\,{2k + 3 + x^{2} \over 1 + x^{2}}
\,{\dd x \over \ln\pars{x}} =
-\int_{0}^{1}{1 \over 1 + x}\,\pars{1 + 2\,{k + 1 \over 1 + x^{2}}}
\,{x - 1 \over \ln\pars{x}}\,\dd x
\\[5mm] = &\
-\int_{0}^{1}{1 \over 1 + x}\,{x - 1 \over \ln\pars{x}}\,\dd x -
2\pars{k + 1}\int_{0}^{1}{1 \over 1 + x}\,{1 \over 1 + x^{2}}
\,{x - 1 \over \ln\pars{x}}\,\dd x
\\[5mm] = &\
-\int_{0}^{1}{1 - x \over 1 - x^{2}}\,{x - 1 \over \ln\pars{x}}\,\dd x -
2\pars{k + 1}\int_{0}^{1}{1 - x \over 1 - x^{4}}
\,{x - 1 \over \ln\pars{x}}\,\dd x =
\bbx{\ds{a_{1} + 2\pars{k + 1}a_{2}}}
\label{1}\tag{1}
\\[5mm] &\
\mbox{where}\quad
a_{n} \equiv
-\int_{0}^{1}{1 - x \over 1 - x^{2n}}\,{x - 1 \over \ln\pars{x}}\,\dd x
\label{2}\tag{2}
\end{align}
With the identity
$\ds{{x - 1 \over \ln\pars{x}} = \int_{0}^{1}x^{t}\,\dd t}$, $\ds{a_{n}}$ becomes:
\begin{align}
a_{n} & =
\int_{0}^{1}\int_{0}^{1}{x^{t + 1} - x^{t} \over 1 - x^{2n}}\,\dd x\,\dd t
\,\,\,\stackrel{x^{2n}\ \mapsto\ x}{=}\,\,\,
{1 \over 2n}
\int_{0}^{1}\int_{0}^{1}
{x^{t/\pars{2n}\ +\ 1/n\ -\ 1}\ -\ x^{t/\pars{2n}\ +\ 1/\pars{2n}\ -\ 1} \over
1 - x}\,\dd x\,\dd t
\\[5mm] = &\
{1 \over 2n}\int_{0}^{1}\bracks{%
\Psi\pars{t + 1 \over 2n} - \Psi\pars{t + 2 \over 2n}}\,\dd t
\end{align}
Here, I used Digamma function identity $\ds{\mathbf{6.3.22}}$ in A & S Table. With
$\ds{\Psi\pars{z} \equiv \totald{\ln\pars{\Gamma\pars{z}}}{z}}$:
\begin{align}
a_{n} & =
\left.\ln\pars{\Gamma\pars{\bracks{t + 1}/\bracks{2n}} \over
\Gamma\pars{\bracks{t + 2}/\bracks{2n}}}\right\vert_{\ t\ =\ 0}^{\ t\ =\ 1} =
\ln\pars{{\Gamma\pars{1/n} \over \Gamma\pars{3/\bracks{2n}}}\,
{\Gamma\pars{1/n} \over \Gamma\pars{1/\bracks{2n}}}}
\\[5mm] = &\
\ln\pars{\Gamma^{2}\pars{1/n} \over \Gamma\pars{3/\bracks{2n}}\Gamma\pars{1/\bracks{2n}}}
\\[5mm]
\mbox{and} &\
\left\{\begin{array}{rcl}
\ds{a_{1}} & \ds{=} &
\ds{\ln\pars{\Gamma^{2}\pars{1} \over \Gamma\pars{3/2}\Gamma\pars{1/2}} =
-\ln\pars{\pi \over 2}}
\\[2mm]
\ds{a_{2}} & \ds{=} &
\ds{\ln\pars{\Gamma^{2}\pars{1/2} \over \Gamma\pars{3/4}\Gamma\pars{1/4}} =
-\ln\pars{\pi \over \pi/\sin\pars{\pi/4}} = -\,{1 \over 2}\,\ln\pars{2}}
\end{array}\right.\label{3}\tag{3}
\end{align}
With \eqref{1} and \eqref{3}:
\begin{align}
&\int_{0}^{1}{1 - x \over 1 + x}\,{2k + 3 + x^{2} \over 1 + x^{2}}
\,{\dd x \over \ln\pars{x}} =
-\ln\pars{\pi \over 2} + 2\pars{k + 1}\bracks{-\,{1 \over 2}\,\ln\pars{2}} =
\bbx{\ds{-\ln\pars{2^{k}\pi}}}
\end{align}
Note that
$\ds{\Gamma\pars{1} = 1\,,\ \Gamma\pars{1 \over 2} = \root{\pi}}$ and the use of $\ds{\Gamma}$-Recurrence Property and Euler Reflection Formula.