$\newcommand\odd{\mathit{odd}}\newcommand\even{\mathit{even}}$You prove it by proving it. Any technique will do.
Ask yourself simply "Do I believe $3n+ 2$ is even then $n$ must by even?" If you do ask yourself "Why do I believe it". If you don't convince you self it does.
I'd say I basically have two options. One strategy is to assume we've already proven:
$\odd*\odd = \odd$
$\odd*\even = \even$
$\even*\even = \even$
$\odd \pm \odd = \even$
$\odd \pm \even = \odd$
$\even \pm \even = \even$.
Then I'd figure I just have to fit $3n + 2=\even$, i.e, $\odd*{???} + \even = \even$
$\odd*{???} = \even - \even = \even$
So $\odd*{???} = \even$. I go through what I know $\odd*\odd = \odd$ and $\odd*\even = \even$ so it has to be that $???$ is even.
This was a case of going through options and seeing what does and doesn't work; so that indicates a proof by contradiction:
Proof: Suppose $n$ is odd. Then $3n$ is also odd as we have proven that $\odd*\odd = \odd$. Then $3n + 2$ is odd as we have already prove that $\odd + \even$ is odd. This is a contradiction.
Or if you don't feel you can rely upon previous result and must replicate them... then replicate them.
Proof: Suppose $n = \odd$ then $n = 2m + 1$ for some $m$. So $3n + 2 = 3(2m+1) + 2 = 6m + 5 = 6m + 4 + 1 = 2(3m+2) + 1$ is an odd number. This is a contradiction.
Or I can figure I need to prove things directly. If I know $3n + 2 = \even = 2k$ for some $k$ will I find that
$3n + 2 = 2k$
$3n = 2k -2 = 2(k-1)$
$n = \frac {2(k-1)}3$ Can I say that $3\nmid 2$ so $3|k-1$? so $n = 2l$ for some $l= \frac {k-1}3$? I can but it's a little more convoluted then I like.
Pf: $3n + 2 = 2k$ so $3n = 2k - 2 = 2(k-1)$ Then $3|2(k-1)$ but $3|k-1$ so $k- 1 = 3l....$ .... and let's not go down this route. It's too convoluted and the way above with a proof by contradiction was simpler.
.... Third option I don't know whether $n$ is even or odd by it must be one or the other.
$n = 2m + k$ where $k = 0$ or $1.
And $3n + 2 = 2j$ for some $j$.
So can I do $3n + 2 = 3(2m + k) + 2 = 2j$?
$6m + 3k + 2 = 2j$
So $3k = 2j - 6m -2 = 2(j-3m -1)=\even$
If $k=1$ then $3k = 3$ is even. If $k = 0$ then $3k = 0$ is even. As these are the only two options, it must be that $k = 0$ and$n = 2m + k = 2m$ is even.
Choose whatever works best for you.