Having called the radius of the circle as $r$, you can find out that the side of the outer square is $2r$. So, the area of the outer square comes out to be $4r^2$.
Now, if you notice carefully, some of the diameters of the circle also act as diagonals of the inner square. So, taking the side of the inner square as $a$, the length of diagonal ie $\sqrt2 a$ is the same as the diameter of the the circle ie $2r$.
$$\implies \sqrt2 a = 2r \implies a = r\sqrt2$$..... (1)
Now, dividing the circle into symmetric halves by a diameter which is also the diagonal of the inner square, you can calculate the area of the white portion inside that half. This area will be the difference of the area of the semicircle and the area of the right triangle, which is a part of the
inner square.
So, area of half white portion $= \frac{\pi r^2}{2} - \frac{1}{2}*a^2$
$$= \frac{\pi r^2}{2} - r^2 = \frac{\pi r^2 - 2r^2}{2}$$ [From (1)]
So, area of whole white portion $=2*\frac{\pi r^2 - 2r^2}{2} = \pi r^2 - 2r^2$
Now, calculating what percentage of the total area is the area of the white portion found above, we have;
$$\frac{\pi r^2 - 2r^2}{4r^2} * 100 = \frac{\pi - 2}{4} * 100 $$
$$= \frac{1.14}{4} * 100 = 28.5\%$$ [Taking $\pi = 3.14$]