Babar, Haitha, Tantor and Pink Honk-Honk are four elephants.
A = $\{$Babar, Haitha, Tantor, Pink Honk-honk$\}$.
A is one thing. It is a set that contains four elephants. But A is not an elephant. A is not even four elephants really. It is a collection of four elephants.
A has four things in it. But A, itself, is one thing.
B = {A}={{Babar, Haitha, Tantor, Pink Honk-honk}} has one thing in it. It has a set in it. It does not have four elephants in it. It is a set with only one thing in it. That thing is a set. (B has something inside it that has four elephants but B, itself, does not have any elephants directly inside it.)
{A} $\ne $ A.
$\emptyset = \{\}$ is set with nothing in it. It is something. It is a set. It is a set with nothing in it.
{A} is a set with one thing in it. {A, $\emptyset$} is a set with with two things in it.
{A} $\ne $ {A, $\emptyset$} because the two sets have different things inside them.
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Note: $A \cup \emptyset = A$ but $\{A, B\} \ne \{A \cup B\}$ so $\{A\} = \{A \cup \emptyset\} \ne \{A, \emptyset\}$.
$\{A,B\}$ is a set with two things in it. Those two things are two sets. $A \cup B$ is one set; a combined set-- all the elements of A and B are dumped out, mixed together and packed up into a new set. So $\{A\cup B\}$ is a set with only one thing int it. That one thing is one set. So $\{A,B\} \ne \{A \cup B\}$.