James Delaney's paper "Groups of Arithmetical Functions" (Mathematics Magazine 78 (2), 83-97, 2005) may be worth a look. Here are some of his main results.
The group $U$ of units of the ring of arithmetic functions (pointwise addition and Dirichlet convolution ($\ast$) as multiplication) can be expressed as the direct sum $U = C \oplus U_M \oplus U_A$, where $C$ is the subgroup of scalar functions, $U_M$ is the subgroup of multiplicative functions, and $U_A$ is the subgroup of what he calls "anti-multiplicative" functions defined by $f(1) = 1$ and $f(p^k) = 0$ when $p^k$ is a prime power with $k > 0$.
He then shows, if $U_1 = U_M \oplus U_A$, then $(U_1, \ast)$ is a divisible torsion-free group and thus can be viewed as a vector space over the rationals. Therefore $U_M$ and $U_A$ are divisible subgroups and are thus complementary subspaces when $U_1$ is regarded as a vector space. This also implies that the $n$th root of a multiplicative function is multiplicative.
Finally, he proves that the functions $\{\epsilon_{\alpha} \lambda_{\beta} | \alpha, \beta \in \mathbb{C}, \beta \neq 0\}$ are linearly independent, where $\epsilon_{\alpha}(n) = n^{\alpha}$ and $\lambda_{\beta}(p_1^{k_1} \cdots p_r^{k_r}) = \beta^{k_1 + \cdots + k_r}$ (a generalization of Liouville's $\lambda$).
I have pretty much paraphrased straight from Delaney's paper. My algebra background is too deficient for me to be able to comment on how interesting (or uninteresting) these results actually are or how well they satisfy what the OP is looking for. (Perhaps someone else could help out with that?)