Trying the Buffalo Way suggested in the comments.
Assume without loss of generality that $a\le b\le c\le d$.
Let $a=x_1$, $b=x_1+x_2$, $c=x_1+x_2+x_3$, $d=x_1+x_2+x_3+x_4$. So $x_i\ge0,i\in[1,4]$
When then want to consider the sign of:
$$\left(\frac{x_1}{3x_1+2x_2+x_3}\right)^2+\left(\frac{x_1+x_2}{3x_1+3x_2+2x_3+x_4}\right)^2+\left(\frac{x_1+x_2+x_3}{3x_1+2x_2+2x_3+x_4}\right)^2+\left(\frac{x_1+x_2+x_3+x_4}{3x_1+2x_2+x_3+x_4}\right)^2-\frac{4}{9}$$
Using brute force gives a disgusting fraction with denominator of:
$$9 (3 x_1+2 x_2+x_3)^2 (3 x_1+2x_2+x_3+x_4)^2 (3 x_1+2 x_2+2x_3+x_4)^2 (3 x_1+3 x_2+2 x_3+x_4)^2$$
and has156 terms in the numerator:
$$4374x_1^6x_2^2+20412x_1^5x_2^3+39366x_1^4x_2^4+40176x_1^3x_2^5+22896x_1^2x_2^6+6912x_1x_2^7+864x_2^8+8748x_1^6x_2x_3+53946x_1^5x_2^2x_3+129600x_1^4x_2^3x_3+158598x_1^3x_2^4x_3+105516x_1^2x_2^5x_3+36456x_1x_2^6x_3+5136x_2^7x_3+8748x_1^6x_3^2+65610x_1^5x_2x_3^2+191727x_1^4x_2^2x_3^2+280260x_1^3x_2^3x_3^2+218367x_1^2x_2^4x_3^2+86820x_1x_2^5x_3^2+13868x_2^6x_3^2+26244x_1^5x_3^3+131058x_1^4x_2x_3^3+258876x_1^3x_2^2x_3^3+250614x_1^2x_2^3x_3^3+118584x_1x_2^4x_3^3+21944x_2^5x_3^3+32481x_1^4x_3^4+118908x_1^3x_2x_3^4+162774x_1^2x_2^2x_3^4+98148x_1x_2^3x_3^4+21925x_2^4x_3^4+21222x_1^3x_3^5+55566x_1^2x_2x_3^5+48414x_1x_2^2x_3^5+13982x_2^3x_3^5+7713x_1^2x_3^6+13050x_1x_2x_3^6+5509x_2^2x_3^6+1476x_1x_3^7+1220x_2x_3^7+116x_3^8+7290x_1^5x_2^2x_4+28350x_1^4x_2^3x_4+43740x_1^3x_2^4x_4+33480x_1^2x_2^5x_4+12720x_1x_2^6x_4+1920x_2^7x_4+8748x_1^6x_3x_4+52488x_1^5x_2x_3x_4+143370x_1^4x_2^2x_3x_4+209952x_1^3x_2^3x_3x_4+167958x_1^2x_2^4x_3x_4+69000x_1x_2^5x_3x_4+11384x_2^6x_3x_4+39366x_1^5x_3^2x_4+180306x_1^4x_2x_3^2x_4+341172x_1^3x_2^2x_3^2x_4+325512x_1^2x_2^3x_3^2x_4+154296x_1x_2^4x_3^2x_4+28848x_2^5x_3^2x_4+64476x_1^4x_3^3x_4+225504x_1^3x_2x_3^3x_4+300762x_1^2x_2^2x_3^3x_4+179304x_1x_2^3x_3^3x_4+39998x_2^4x_3^3x_4+52002x_1^3x_3^4x_4+132408x_1^2x_2x_3^4x_4+113484x_1x_2^2x_3^4x_4+32534x_2^3x_3^4x_4+22302x_1^2x_3^5x_4+37044x_1x_2x_3^5x_4+15474x_2^2x_3^5x_4+4878x_1x_3^6x_4+3982x_2x_3^6x_4+428x_3^7x_4+4374x_1^6x_4^2+18954x_1^5x_2x_4^2+39123x_1^4x_2^2x_4^2+48276x_1^3x_2^3x_4^2+35658x_1^2x_2^4x_4^2+14280x_1x_2^5x_4^2+2360x_2^6x_4^2+24786x_1^5x_3x_4^2+98172x_1^4x_2x_3x_4^2+166212x_1^3x_2^2x_3x_4^2+147888x_1^2x_2^3x_3x_4^2+67668x_1x_2^4x_3x_4^2+12504x_2^5x_3x_4^2+51759x_1^4x_3^2x_4^2+167184x_1^3x_2x_3^2x_4^2+210438x_1^2x_2^2x_3^2x_4^2+121080x_1x_2^3x_3^2x_4^2+26558x_2^4x_3^2x_4^2+51192x_1^3x_3^3x_4^2+124074x_1^2x_2x_3^3x_4^2+102816x_1x_2^2x_3^3x_4^2+28928x_2^3x_3^3x_4^2+25911x_1^2x_3^4x_4^2+41676x_1x_2x_3^4x_4^2+17072x_2^2x_3^4x_4^2+6486x_1x_3^5x_4^2+5190x_2x_3^5x_4^2+637x_3^6x_4^2+5832x_1^5x_4^3+20574x_1^4x_2x_4^3+30780x_1^3x_2^2x_4^3+24642x_1^2x_2^3x_4^3+10488x_1x_2^4x_4^3+1864x_2^5x_4^3+19764x_1^4x_3x_4^3+58320x_1^3x_2x_3x_4^3+67752x_1^2x_2^2x_3x_4^3+36756x_1x_2^3x_3x_4^3+7792x_2^4x_3x_4^3+25596x_1^3x_3^2x_4^3+57996x_1^2x_2x_3^2x_4^3+45636x_1x_2^2x_3^2x_4^3+12442x_2^3x_3^2x_4^3+15606x_1^2x_3^3x_4^3+23916x_1x_2x_3^3x_4^3+9506x_2^2x_3^3x_4^3+4488x_1x_3^4x_4^3+3488x_2x_3^4x_4^3+494x_3^5x_4^3+2916x_1^4x_4^4+7938x_1^3x_2x_4^4+8469x_1^2x_2^2x_4^4+4272x_1x_2^3x_4^4+864x_2^4x_4^4+6480x_1^3x_3x_4^4+13572x_1^2x_2x_3x_4^4+9984x_1x_2^2x_3x_4^4+2608x_2^3x_3x_4^4+5148x_1^2x_3^2x_4^4+7380x_1x_2x_3^2x_4^4+2816x_2^2x_3^2x_4^4+1728x_1x_3^3x_4^4+1292x_2x_3^3x_4^4+214x_3^4x_4^4+648x_1^3x_4^5+1242x_1^2x_2x_4^5+840x_1x_2^2x_4^5+208x_2^3x_4^5+864x_1^2x_3x_4^5+1128x_1x_2x_3x_4^5+408x_2^2x_3x_4^5+354x_1x_3^2x_4^5+252x_2x_3^2x_4^5+50x_3^3x_4^5+54x_1^2x_4^6+60x_1x_2x_4^6+20x_2^2x_4^6+30x_1x_3x_4^6+20x_2x_3x_4^6+5x_3^2x_4^6$$
All the co-efficients of the terms are positive and $x_i\ge0,i\in[1,4]$ so the entire expression is positive.
Reflection
Buffalo Way is terrible.
Also I don't know how to format that eyesore of a numerator nicely on this site.