Let $X$ be a discrete random variables with values in the set $\{x_1,\ldots, x_n\}\subset\mathbb{R}$. Denote by $p_i$ the probability that $X=x_i$. We can then regard the variance $\mbox{Var}(X)$ as a function of the vector $p\in \Delta^{n-1}\subseteq\mathbb{R}^n$.
Will it be a concave function of $p$? With $n=2$, we get
$$\mbox{Var} (X)=p_1p_2(x_1-x_2)^2=p_1(1-p_1)(x_1-x_2)^2$$
which is concave. I'm not sure how to generalize this beyond two dimensions though.