For each $n \in \mathbb N$ let $\mathfrak e_n : 2^{\mathbb N} \to 2$ be the evaluation map at $n$; i.e., $\mathfrak e_n (f) = f(n)$ for each $f \in 2^{\mathbb{N}}$. Letting $A = \{ \mathfrak{e}_n : n \in \mathbb{N} \}$, wwe are looking for $\overline A$ in $2^{2^{\mathbb N}}$.
Given any $\mathfrak f \in 2^{2^{\mathbb N}}$, a neighborhood basis for $\mathfrak f$ is described as follows. For $f_1, \ldots , f_k \in 2^{\mathbb N}$, define $$U_{\mathfrak f;f_1,\ldots,f_k} = \{ \mathfrak g \in 2^{2^{\mathbb N}} : ( \forall i \leq k ) ( \mathfrak g (f_i) = \mathfrak f (f_i) ) \}.$$ Then $\{ U_{\mathfrak f;f_1,\ldots,f_k} : f_1 , \ldots , f_k \in 2^{\mathbb N} \}$ constitutes a neighborhood basis for $\mathfrak f$.
Now $\mathfrak f \in \overline A$ iff $A \cap U_{\mathfrak f;f_1,\ldots,f_k} \neq \emptyset$ for all $f_1 , \ldots , f_k \in 2^{\mathbb N}$. That is, given any $f_1 , \ldots , f_k \in 2^{\mathbb N}$ there is an $n \in \mathbb N$ such that $\mathfrak e_n \in U_{\mathfrak f;f_1,\ldots,f_k}$, or, given $f_1 , \ldots , f_k \in 2^{\mathbb N}$ there is an $n \in \mathbb N$ such that $\mathfrak f (f_i) = \mathfrak e_n(f_i) = f_i(n)$ for all $i \leq k$. Putting this into words, $\mathfrak f \in \overline A$ iff $\mathfrak f$ is "everywhere locally an evaluation map at some $n \in \mathbb{N}$".
This description is probably not as simple as you would like, but we can get a bit out of this.
- Neither constant function belongs to $\overline A$. (Given constant $\mathfrak{f} : f \mapsto j$, consider the constant function $f : n \mapsto 1-j$.)
- Given $f \in 2^{\mathbb N}$, let $\hat f$ denote the complement of $f$: $\hat f(n) = 1 - f(n)$ for all $n \in \mathbb N$. If $\mathfrak f \in \overline A$, then $\mathfrak f(\hat f) = 1 - \mathfrak f(f)$ for all $f \in 2^{\mathbb N}$. (Given $f$ there is an $n$ such that $\mathfrak f(\hat f) = \hat f(n)$ and $\mathfrak f(f) = f(n)$. Then $\mathfrak f(\hat f) = \hat f(n) = 1 - f(n) = 1 - \mathfrak f(f)$.)
- In a bit more generality than the above point, suppose $f_1, \ldots , f_k$ is a "partition of unity", i.e., for each $n \in \mathbb N$ exactly one of $f_1(n), \ldots , f_k(n)$ is $1$. If $\mathfrak f \in \overline A$, then $\mathfrak f(f_i) = 1$ for exactly one $i \leq k$.
- Define a partial ordering $\preceq$ on $2^{\mathbb N}$ by $f \preceq g$ iff $f(n) \leq g(n)$ for all $n \in \mathbb N$. If $\mathfrak f \in \overline A$, then $\mathfrak f$ is non-decreasing with respect to $\preceq$. (Given $f \preceq g$ there is an $n$ such that $\mathfrak f(f) = f(n)$ and $\mathfrak f(g) = g(n)$. Then $\mathfrak f(f) = f(n) \leq g(n) = \mathfrak f(g)$.)