Well, in theory, if you have shown $\mathbb Q $ is countable, we have a bijection $j:\mathbb N\rightarrow \mathbb Q $.
We create a new bijection, k, where $k (1)=\pi; k (2)=e;\forall n>2| k (n)=j (n-2) $.
Of course if we want to add two (or any finite number of elements) elements to an uncountable set it should be easy but seems hard.
Other folks have shown this with the reals. Generalized it's...
What we do (we can assume countable choice, can't we?) Is arbitrarily pick a countable subset $P=${$x_1,x_2... $}. Then we can define bijective $j|X \rightarrow X \cup\{a,b\}$ as $j (x_1)=a;j (x_2)=b$ for $x_i\in P; i >2;j (x_i)=x_{i-2}$ and for $x \not \in P;j (x)=x $.