White noise can only be defined in the sense of distributions or as a measure. A good definition can be found in Adler and Taylor (2007, Sec. 1.4.3), see also this SE answer.
To calculate second moments you want to use stochastic integration Adler and Taylor (2007, sec. 5.2) (also see below) for deterministic functions $f,g$
$$
\mathbb{E}[W(f)W(g)]
\overset{\text{def.}}=\mathbb{E}\Bigl[\Bigl(\int f(x)W(dx)\Bigr)\Bigl(\int g(x)W(dx)\Bigr) \Bigr]
=\int f(x)g(x) dx, \tag{1}
$$
which can be viewed as a special case of the Itô Isometry.
Convolution
We can consider convolutions as a special case
$$
(f*W)(t) = \int f(t-s)W(ds) = W(f(t-\cdot))
$$
then the covariance function (expectation is zero) is given by
$$
C(t,s) = \mathbb{E}[ (f*W)(t)(f*W)(s)] = \int f(t-x)f(s-x)dx
$$
Stochastic Integration
The trick to prove (1), is to show that the mapping
$$
W:\begin{cases}
L^2(\mathbb{R}^n, \mathcal{B}, \nu)
&\to L^2(\Omega, \mathcal{A}, \mathbb{P})\\
f &\mapsto W(f) := \int f(t) W(dt)
\end{cases}
$$
preserves the scalar product.
We first consider simple functions $f=\sum_{i=1}^n a_i \mathbf{1}_{A_i}$ for disjoint $A_i$, then
$$
W(f)=\int f(t) W(dt) \overset{\text{def.}}= \sum_{i=1}^n a_i W(A_i)
$$
Comment: in particular the expectation is zero and variance given by $\sum_{i=1}^n a_i \nu(A_i)$ considering the definition of $W$.
To calculate the scalar product between $f$ and $g=\sum_{i=1}^n b_i \mathbf{1}_{B_i}$ we assume without loss of generality $A_i=B_i$ (consider all of their interesections). Then
$$\begin{aligned}
\langle W(f), W(g) \rangle_{L^2(\mathbb{P})}
&= \mathbb{E}\Bigl[\sum_{i=1}^n a_i W(A_i) \sum_{j=1}^n a_j W(A_j)\Bigr]\\
&= \sum_{i=1}^n a_i b_i \mathbb{E}[W(A_i)^2]\\
&= \int f(t) g(t) \nu(dt)\\
&= \langle f, g\rangle_{L^2(\nu)}
\end{aligned}$$
Since the simple function are dense in $L^2$ and the scalar product is continuous we can deduce that $W$ is an isometry (where $W(f)$ for general $f$ is defined as the limit of $W(f_n)$ for simple functions $f_n$ approximating $f$). (1) then directly follows from the respective definitions of the scalar product (i.e. the second and penultimate term).