I'm new to category theory and I'm struggling to get an intuition for very basic concepts. Assuming the notation that we characterize dual equivalence for categories $A$ and $B$ by an equivalence functor(<=> full, faithful, isomorphism-dense/essentially surjective) between $A^{\text{op}}$ and $B$.
General questions:
1.a. Is there some deeper meaning to the property of a category to be dually equivalent to itself? I.e. has the sub-conglomerate of these categories in $Cat$ important properties?
1.b. In what respect does dual equivalence of a category to itself generalize self-duality?
Examples:
2.a. Are there some instructive examples for categories which are dually equivalent to themselves?
Only the category of finite dimensional vector spaces and categories which are groupoids(even dually isomorphic to themselves) come to my mind (e.g. category of relations $Rel$, sets as objects, relations as morphisms).
Counterexamples:
So far it seems to me, that the categories of sets $Set$(and of finite sets $FinSet$), topological spaces $Top$, magmas $Mag$, Semigroups $Sem$, sets structured with relations $Rel_n Set$ (sets with $n$-relations as objects and maps perserving these as morphisms) are not dually equivalent to themselves since they have initial/terminal objects which aren't zero objects.
3.a. Why is the category of $\mathbb{k}$-vector spaces $Vec_{\mathbb{k}}$ not dually equivalent to itself?
I would argue: Assume an equivalence functor $F: Vec_{\mathbb{k}} \rightarrow Vec_{\mathbb{k}}^{op}$, $\aleph_0$-dim. $V_0$ and $\aleph_1$-dim. $V_1$ as $Vec_{\mathbb{k}}$-objects. To be full/faithful $F$ has to map infinite-dim. vectorspaces within their isomorphism-classes, i.e. $V_i\cong F(V_i)$. But since equivalences preserve/reflect mono/epimorphisms I get a contradiction by duality: $\emptyset=epi_{Vec_{\mathbb{k}}}(V_0,V_1)\cong epi_{Vec_{\mathbb{k}}^{op}}(F(V_0),F(V_1))=mono_{Vec_{\mathbb{k}}}(F(V_1),F(V_0))\neq \emptyset$.
I would like to argue similarly for the category of groups $Grp$, but I have no idea about the general cardinality of hom-sets in $Grp$, so...
3.b. Why is the category of groups $Grp$ not dually equivalent to itself?
3.c. What about the categories of monoids $Mon$?
3.d. Are there more instructive counterexamples?