Use: $P_n(x)=\frac{1}{2^n}\sum_{m=0}^M(-1)^m\frac{(2n-2m)!}{m!(n-m)!(n-2m)!}x^{n-2m}$ where M=n/2 if even, (n-1)/2 if n odd, to prove $P_{2n}(0)=(-1)^n\frac{(2n)!}{2^{2n}(n!)^2}$ and $P_{2n+1}(0)=0$.
There's something I'm missing. If x=0, only the case where n=0 ($a_0$) will be non zero and equal 1. In case I didn't reproduce whatever it is that I'm missing, this problem is from Asmar Partial differential equations chpt 5.5 problem 2b.