From the Ergodic Theory viewpoint, the simplicity of the eigenvalue $1$ for the Koopman operator is merely a restatement of the Ergodicity of the transformation $T$. In fact, the following statements are equivalents (Walters, An Introduction to Ergodic Theory):
1) $T$ is ergodic.
2) Whenever $f$ is measurable and $f\circ T (x)=f(x)$ for every $x$ implies that $f$ is constant a.e.
3) Whenever $f$ is measurable and $f\circ T (x)=f(x)$ a.e. implies that $f$ is constant a.e.
4) Whenever $f\in L^2$ and $f\circ T (x)=f(x)$ for every $x$ implies that $f$ is constant a.e.
5) Whenever $f\in L^2$ and $f\circ T (x)=f(x)$ a.e. implies that $f$ is constant a.e.
The statement of (5) says exactly that $1$ is a simple eigenvalue of $U_T$. A bit more can be said about eigenvalues (again, see Walters)
If $U_Tf=\lambda f$, with $f\in L^2$, then $|\lambda|=1$ and $|f|$ is constant.