The difference between supremum and maximum is that for bounded, infinite sets, the maximum may not exist, but the supremum always does. Consider the set $(0,1)$. Does this set contain a largest element? The answer is no because for any $x \in (0,1)$, $\tfrac{x+1}{2}$ is also in $(0,1)$ and $x < \tfrac{x+1}{2}$. That is, for any $x \in (0,1)$, we can find an element in $(0,1)$ which is larger than $x$. Thus there is no maximal element of $(0,1)$. By contrast, the supremum is the least upper bound for the set. The supremum does not need to be in the set. For $(0,1)$, the supremum is 1. This means that $1$ is an upper bound for $(0,1)$ [which is obvious] and that no number smaller than $1$ is an upper bound for $(0,1)$ [which follows from the above reasoning]. Whenever the maximum exists, it is equal to the supremum. Conversely, if the supremum lies in the set, then the maximum exists and is equal to this supremum.
The difference between minimum and infimum is similar. In my example, $(0,1)$ has no minimum, but the infimum is 0.
For your set, we see the sequence goes $$1, \,\,\,\,\, 2/3, \,\,\,\,\, 3/5, \,\,\,\,\, 4/7, \ldots.$$ The sequence is clearly decreasing. The number 1 is in the set and no other member of the set is larger than 1. Hence 1 is a maximum for the set. Since the maximum exists, it is equal to the supremum, so the supremum is also 1. There is no minimum element since for any element $x_n$ of the set, the value $x_{n+1}$ is less than $x_n$. However, the infimum is 1/2. To see this, we note that all members are greater than 1/2, so 1/2 is a lower bound. To be the infimum, it needs to be the greatest lower bound, so you need to prove that $1/2 + a$ is not a lower bound for any $a > 0$. Indeed, if $a > 0$, taking $n$ large enough that $1/(4n-2) < a$ shows that $$x_n = \frac{n}{2n -1} = \frac{n-1/2 + 1/2}{2n-1} = \frac 1 2 + \frac 1{4n-2} < \frac 1 2 + a.$$ Thus we have found a member of the sequence which is smaller than $1/2 + a$ so $1/2 + a$ is not a lower bound for the sequence. Hence $1/2$ is the infimum.