Here's a brute force approach. There's probably a more elegant way of doing it.
The two curves can be written as $y=x^c$ and $y=x^{1/c}$. They always intersect at $x=0$ and $x=1$ (for $c=1$ the curves coincide).

The derivatives of the two curves are $c x^{c-1}$ and $c^{-1}x^{1/c-1}$ respectively.
For $0<c\neq1$ the angle between them at $x=0$ is clearly always $\pi/2$.
At $x=1$ we want the angle between them to be $\pi/4$, so
$$ \tan^{-1}(c) - \tan^{-1}(1/c) = \pm\frac\pi4 \implies c = \pm 1+\sqrt2 $$
The two solutions just reflect the fact that you can swap the two curves, or equivalently, set $c\to1/c$.
There are also two negative solutions to the above equation which are excluded by the question. These are also valid curves and solutions, which can be obtained by the transformation $x \to 1/x$.