A few comments about the general situation:
The spectral radius is not a norm on the space of all $n \times n$ matrices, for $n>1$. This is because there exist nonzero matrices with zero spectral radius, e.g.
$$\begin{bmatrix} 0 & 1 \\ 0 & 0 \end{bmatrix}.$$
However, given a matrix $A$ with spectral radius $\rho(A)$, for every $\varepsilon > 0$ there exists an operator norm $\| \cdot \|$ such that $\| A \| \leq \rho(A) + \varepsilon$.
At the same time, if a matrix is self-adjoint with respect to an inner product, then its operator norm with respect to this inner product and its spectral radius correspond.
In view of the preceding comments, to find a positive matrix whose Euclidean operator norm is larger than its spectral radius, you should look for something which is very asymmetric, like
$$\begin{bmatrix} 1 & 1 \\ \varepsilon & 1 \end{bmatrix}$$
where $0<\varepsilon \ll 1$. This has trace $2$ and determinant $1-\varepsilon$, so the eigenvalues are $1+\sqrt{\varepsilon}$ and $1-\sqrt{\varepsilon}$. On the other hand the Euclidean operator norm is at least $\sqrt{2}$ independent of $\varepsilon$, as you can see by multiplying this matrix with the unit vector $e_2$. So this gives an example whenever $\sqrt{\varepsilon}<\sqrt{2}-1$; concretely, you can take $\varepsilon=0.1$.