Standard definition of prime model over a set is that: $M\vDash T$ is said to be a prime model extension of a set $A$ if $A\subset M$ and any partial elementary map $A\rightarrow N$ ($N\vDash$) extend elementary $M\rightarrow N$.
So far so good. But I am confused when I got to a standard exercise. First, it is not clear whether $A$ can be any sets, or must be a substructure. So if you are given a set $A$, any set $A$, can you ask the question of whether there are any prime model extension over $A$, even without having given interpretation to symbols? For example, is it meaningful to ask "is there any prime model extensions for the theory of algebraically closed field of characteristic 0 over the sphere $S^{5}$?"?
The exercise that cause me trouble here is that:
Let $L=\{<,U\}$ be a language (U unary, < binary relation), and $T$ be dense linear order without endpoints together with sentence that say that the set defined by $U$ and its complement are both dense. Let $M\vDash T$ and let $A=U^{M}$. Show that there are no prime model extensions of $A$.