The intersection of two varieties is given by the sum of their ideals. So you're looking at the ideal generated by the union of the generators of $V_V$ and $V_S$.
Immediately we see that both $x_1^2-x_0x_3$ and $x_0x_3-x_1x_2$ are generators of $I=I_{S \cap V}$. But this implies that $x_1^2-x_1x_2=x_1(x_1-x_2)$ is a generator of $I$. Thus $I$ is reducible.
We can try to find the intersection directly. A point on the intersection must satisfy $x_1(x_1-x_2)=0$. So assume $x_1 \neq x_
2$. Then we must have $x_1=0$. Then the ideal reduces to
$$
I = (x_0x_3,x_4x_0,x_2x_3,x_2x_4,x_2^2-x_5x_0,x_3x_5-x_4^2,x_0x_5,x_2x_5-x_3x_4)
$$
Removing duplicates and simplifying, this is
$$
I = (x_0x_3,x_0x_4,x_0x_5,x_2x_3,x_2x_4,x_2^2,x_3x_5-x_4^2,x_2x_5-x_3x_4)
$$
This is clearly reducible. For example, $x_0x_3=0$. Assume first $x_0=0$. Then the (radical of the ideal is)
$$
(x_2,x_3x_5-x_4^2,x_3x_4)
$$
This decomposes as well. Assume first $x_3=0$. Then the ideal is $(x_2,x_4^2)$. Hence we have found a point on the intersection, namely the one given by ideal $(x_1,x_0,x_3,x_2,x_4)$. This is the point $(0:0:0:0:1)$ in $\mathbb P^5$.
If we assume $x_3=0$ above, we get by the same procedure the ideal $(x_0x_5,x_2,x_4)$. This gives us two more points, namely $(0:0:0:0:0:1)$ and $(1:0:0:0:0:0)$.
Lastly, assume $x_1=x_2$. Then the equations simplifly to
$$
(x_1^2-x_0x_3,x_1^2-x_0x_4,x_1x_4-x_1x_3,x_1x_4-x_1x_4,x_1^2-x_0x_5,x_3x_5-x_4^2,x_0x_3-x_1^2,x_0x_5-x_1x_4,x_1x_5-x_3x_5)
$$
We can assume $x_1 \neq 0$, since we have treated that case already. Hence we can divide by $x_1$ everywhere.
$$
(x_1^2-x_0x_3,x_1^2-x_0x_4,x_3-x_4,x_1^2-x_0x_5,x_3x_5-x_4^2,x_0 x_3-x_1^2,x_0x_5-x_1x_4,x_1x_5-x_3x_5).
$$
Not too big a simplification, but now we see that $x_3=x_4$. This again simplifies a lot, since we get that $x_3x_5-x_3^2=0$. This implies either $x_3=0$ or $x_5=x_3$. First assume $x_3=0$. Then a similar calculation gives the point $(0:0:0:0:0:1)$ which we have already found.
Assume now $x_3 \neq 0$. Then $x_3=x_5$, so we get
$$
(x_1^2-x_0x_3,x_0x_3-x_1^2,x_0x_3-x_1x_3,x_1x_3-x_3^2)
$$
Since $x_3 \neq 0$, we get $x_0=x_1$. And $x_1=x_3$. All in all, we get the point $(1:1:1:1:1:1)$.
In conclusion: the intersection is a union of 4 points.
If you have Macaulay2, all this could have been done as follows:
i23 : decompose ideal mingens (I1 + I2)
o23 = {ideal (x - x , x - x , - x + x , x - x , x - x ), ideal (x , x , x , x , x ), ideal (x ,
2 4 1 4 4 5 0 4 3 4 4 2 1 0 3 4
-------------------------------------------------------------------------------------------------
x , x , x , x ), ideal (x , x , x , x , x )}
2 1 5 0 4 2 1 5 3
Here $I1,I2$ are the ideals of the Veronese and Segre variety resepctively. We see that the ideals we get correspond to the points found above.