For a given positive semi-definite matrix $A$, expressed using singular value decomposition as: $A=UD^2U'$ (subject to the orthonormality conditions), any positive semi-definite matrix $X$ that satisfies $A - X \succeq 0$ can be expressed in terms of $X= U Z^2 U'$ subject to the constraint that $\forall i .D_{ii}^2 - Z_{ii}^2 \geq 0$.
Please bear in mind, the eigenvalues of $X$, i.e. $Z_{ii}^2$ can appear in any order, as long as they satisfy the above constraint.
I have done some numerical examples and it seems to support the statement, but I don't have a proof for it yet.
I really appreciate a counterexample to the statement or a proof.